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hmm that seems odd, perhaps a metamask quirk? I personally haven’t attempted to send an NFT through Metamask directly, I always use the „Transfer“ button in OpenSea. But yeah, there’s nothing about the Ledger that makes it so you can’t send NFTs.
I did some googling and yeah it looks like Metamask only supports NFT transfers using the mobile app. This seems to be the case, Ledger or no Ledger. Maybe try transferring it using OpenSea’s UI and see if that works?